Synthesis,Crystal Structure and Electrochemical Property of the Ferrocenyl Schiff-base (E)-N’(Ferrocene Ethylidene)Picolino Hydrazide

被引：2

作者：

李传碧

孙丽娟

张首才

张爱萍

富超

王家军

机构：

[1] Chemistry College of Jilin Normal University

[2] Key Laboratory of Preparation and Applications of Environmental Friendly Materials,Jilin Normal University

来源：

结构化学 | 2011年 / 30卷 / 03期

关键词：

crystal structure; electrochemical property; Schiff-base; acetylferrocene;

D O I：

10.14102/j.cnki.0254-5861.2011.03.009

中图分类号：

O621.3 [有机合成化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel Schiff-base compound based on ferrocene C18H17OFeN3 (1) has been synthesized and characterized by X-ray diffraction. The title compound crystallizes in monoclinic, space group P21/c with a = 19.2343(17), b = 10.5084(9), c = 7.9373(7) , β = 97.7740°, Z = 4, V = 1589.6(2) 3, Dc = 1.451 g/cm3, μ(MoKα) = 0.956 mm-1, F(000) = 720, the final R = 0.0343 and wR = 0.0973 for 2759 observed reflections (I > 2σ(I)). Electrochemical measurements exhibit that compound 1 undergoes a reversible one-electron redox process.

引用

页码：308 / 311

页数：4