Synthesis, Structure and Fluorescent Property of a Cadmium (II) Polymer

被引：0

作者：

XIA ShengQing HU ShengMin ZHANG JianJun DU WenXin WU XinTao State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian China ^{[350002
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机构：

来源：

结构化学 | 2004年 / 08期

关键词：

supramolecule; cadmium; fluorescent;

D O I：

10.14102/j.cnki.0254-5861.2004.08.012

中图分类号：

O631 [高分子物理和高分子物理化学];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new cadmium(II) coordination polymer with benzenetricarboxylate{Cd2- (Htma)2(H2O)2}}n 1 (Htma = 1-carboxybenzene-2,4-dicarboxylate) has been synthesized by hydro- thermal reaction. 1 crystallizes in triclinic, space group P?with a = 6.9990(8), b = 7.0564(8), c = 10.096(1) ? = 83.438(1), = 86.357(2), = 69.233(2)? V = 463.02(9) 3, Dc = 2.428 g/cm3, F(000) = 328, Mr = 677.08, m(MoKa) = 2.382 mm-1, Z = 1, the final R = 0.0284 and wR = 0.0772 for 1540 observed reflections (I≥2s(I)). The structure of 1 consists of centrosymmetric dinuclear units with all metal centers being six-coordinated, which adopt a distorted octahedral configuration and lead to the formation of three-dimensional microporous framework with size of about 3 ??8 ? Fluoerescent measurement showed that 1 exhibits intense fluorescent emission.

引用

页码：898 / 901+842 +842

页数：5