Synthesis,characterization and fluorescence properties of a novel rare earth complex for anti-counterfeiting material

被引:7
|
作者
赵苗 [1 ]
西鹏 [1 ,2 ]
顾晓华 [3 ]
李宗仁 [1 ]
高明明 [1 ]
程博闻 [1 ]
机构
[1] State Key Laboratory of Hollow Fiber Membrane Materials and Processes,Tianji n Polytechnic University
[2] School of Materials Science and Engineering,Qiqihar University
[3] State Key Laboratory of Poly mer Physics and Chemistry,Joint Laboratory of Polymer Science and Materials,In stitute of Chemistry,the Chinese Academy of Sciences
关键词
rare earths; multicarboxyl; complex; fluorescence;
D O I
暂无
中图分类号
TG146.45 [];
学科分类号
080502 ;
摘要
A novel ligand with two ester groups,two benzene rings and two carbox yl groups was synthesized. The composition and structure of the ligand were char acterized by the Fourier transform infrared spectroscopy(FT-IR) ,nuclear magnet ic resonance spectrum(NMR) and UV spectrometer. The rare-earth complex with the ligand and 1,10-phenanthroline(phen) was synthesized and structurally charact erized by FT-IR,TG and fluorescent spectrometer. The results showed that the no vel multicarboxyl ligand could efficiently transfer the energy to Eu3+ ions in t he complex and sensitize the luminescence of the rare earth ions,and the comple x could emit strong fluorescence of the rare earth ions.
引用
收藏
页码:75 / 78
页数:4
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