Bifunctional rare earth metal catalysts for conversion of CO2 and epoxides into cyclic carbonates

被引:0
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作者
Yao Quanyou
Shi Yize
Wang Yaorong
Zhu Xuehua
Yuan Dan
Yao Yingming
机构
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暂无
中图分类号
TQ225.52 []; TQ426 [催化剂(触媒)];
学科分类号
080502 ; 0817 ; 081705 ;
摘要
A series of bifunctional rare earth metal complexes bearing zwitterionic amino-bis(phenolato) ligands were synthesized and structurally characterized.These complexes were applied as catalysts for the synthesis of cyclic carbonates from epoxides and CO2.Lanthanum complex 1Lawas most active,converting terminal epoxides into the cyclic carbonates in moderate to excellent yields at 40℃in the presence of 1 bar CO2.
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页码:31 / 31
页数:1
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