Controlling flexibility of metal–organic frameworks

被引：9

作者：

JiePeng Zhang ^{[1
]}

HaoLong Zhou ^{[1
]}

DongDong Zhou ^{[1
]}

PeiQin Liao ^{[1
]}

XiaoMing Chen ^{[1
,2
]}

机构：

[1] MOE Key Laboratory of Bioinorganic and Synthetic Chemistry,School of Chemistry,Sun Yat-Sen University

[2] Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University

来源：

National Science Review | 2018年 / 5卷 / 06期

关键词：

porous coordination polymers; metal–organic frameworks; flexibility; dynamism; adsorption; structural transformation;

D O I：

暂无

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

Framework flexibility is one of the most important characteristics of metal–organic frameworks(MOFs),which is not only interesting, but also useful for a variety of applications. Designing, tailoring or controlling framework flexibility of MOFs is much more difficult than for static structural features such as the framework topology and pore size/shape. Nevertheless, with in-depth understanding of the relationship between framework flexibility and the host framework structure, guest loading and other aspects such as the crystal size/morphology and external physical environment, some strategies have been developed for controlling the flexibility of MOFs and the corresponding properties, which are summarized and discussed in this review.

引用

页码：907 / 919

页数：13

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