SYNTHESIS AND CATALYTIC PROPERTY OF POLYSTYRENE SUPPORTED PHENYLALANINE SCHIFF BASE COMPLEX OF Mn(Ⅱ) IN AEROBIC OXIDATION OF CYCLOHEXENE

被引：0

作者：

ZHAO Ganqing XIE Jimin LU Xiaoqing SUN Lu College of Chemistry Chemical Engineering Jiangsu University Zhenjiang China College of Chemistry and Chem Eng Pingdingshan University Pingdingshan China ^{[1
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机构：

来源：

Chinese Journal of Reactive Polymers | 2006年 / 02期

关键词：

Aerobic oxidation; polystyrene supported manganese complex; Cyclohexene; phenylalanine;

D O I：

暂无

中图分类号：

O621.2 [有机化合物性质];

学科分类号：

070303 ; 081704 ;

摘要：

The polystyrene supported phenylalanine Schiff base complex of Mn(II) (PS-Sal-Phe-Mn) was prepared with chloromethylated styrene polymer beads, 2,4-dihydroxybenzaldehyde, L-phenylalanine and manganese (II) acetate tetrahyrate., The polymeric ligand and the complex were characterized by FT-IR,, small area X-ray photoelectron spectroscopy (XPS), and ICP-AES. In the presence of the manganese complex, cyclohexene (1) was effectively oxidized by molecular oxygen without reductant. The major products of the reaction were 2-cyclohexen-1-ol (2), 2-cyclohexen-1-one (3) and 2-cyclohexen-1- hydroperoxide (4), which was different with typical oxidation of cyclohexene. The influence of reaction temperature and additive for oxidation had been studied. The selectivity of 2-cyclohexen-1-hydroperoxide varied with reaction time and different additives. The mechanism of cyclohexene oxidation had also been discussed.

引用

页码：174 / 180

页数：7