A separation processing for industrial rare earth feed solution by phosphonium ionic liquid type saponification strategy

被引：0

作者：

董亚敏 ^{[1
,2
]}

郭向广 ^{[1
,2
]}

王艳良 ^{[1
,2
]}

赵泽原 ^{[1
,2
]}

黄超 ^{[1
,3
]}

孙晓琦 ^{[1
,2
]}

机构：

[1] Xiamen Institute of Rare Earth Materials,Haixi Institute,Chinese Academy of Sciences

[2] Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences

[3] School of Metallurgy and Chemical Engineering,Jiangxi University of Science & Technology

来源：

JournalofRareEarths | 2017年 / 35卷 / 03期

基金：

中国国家自然科学基金;

关键词：

heavy rare earth; ionic liquid; saponification; fractional extraction;

D O I：

暂无

中图分类号：

O614.322 [];

学科分类号：

070301 ; 081704 ;

摘要：

A novel ionic liquid type saponification processing based on quaternary phosphonium type bifunctional IL was developed for yttrium separation from ion-adsorbed rare earth deposit.The extractabilities of([trihexyl(tetradecyl)phosphonium][sec-octylphenoxy acetate]([P][SOPAA]) were pronouncedly higher than those of sec-octylphenoxy acetic acid(HSOPAA),a mixture of HSOPAA and[P]Cl for rare earth elements(REEs).The ion association extraction mechanism contributed to avoiding the numerous saponification procedures using alkali and resulting in saponification wastewater.After 13 stages of extraction and 6 stages of scrubbing sections,the Y(Ⅲ) was successfully separated from industrial heavy RREs feed,the purity of Y(Ⅲ) in raffinate was approximately to be 98.9%.Stripping by distilled water was effectively achieved for REEs,which contributed to the decreased consumption of acid to a considerable extent.

引用

页码：290 / 299

页数：10

共 22 条

[21] Reversed micellar solubilization extraction and separation of thorium(IV) from rare earth(III) by primary amine N1923 in ionic liquid [J].

Zuo, Yong ;

Chen, Ji ;

Li, Deqian .

SEPARATION AND PURIFICATION TECHNOLOGY, 2008, 63 (03) :684-690

[22] Surface-induced nano-generator utilizing a thermo-responsive smart window based on ionic liquid aqueous solution that exhibits lower critical solution temperature type phase separation [J].

Goda, Kazuya ;

Kataoka, Wataru ;

Araki, Rina .

Journal of Ionic Liquids, 2024, 4 (02)

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