Synthesis and Physicochemical Properties of L-(+)-a-(Positive Butyl)-Leucine Ethyl Ester Chiral Ionic Liquids

被引：1

作者：

田甜

胡小玲

GUAN Ping

TANG Yimei

WANG Hongli

机构：

[1] DepartmentofAppliedChemistry,SchoolofNaturalandAppliedScience,NorthwesternPolytechnicalUniversity,TheKeyLaboratoryofSpaceAppliedPhysicsandChemistry,MinistryofEducation

来源：

Journal of Wuhan University of Technology(Materials Science) | 2018年 / 33卷 / 01期

关键词：

L-(+)-α-(positive butyl)-leucine ethyl ester; chiral ionic liquids; systhesis; characterization; physicochemistry properties;

D O I：

暂无

中图分类号：

O645.1 [液态溶液];

学科分类号：

070304 ; 081704 ;

摘要：

L-（+）-α-（positive butyl）-leucine ethyl ester bromide chiral ionic liquid was synthesized by using microwave-assisted synthesis method and L-（+）-α-（positive butyl）-leucine ethyl ester terafluoroborate and hexafluorophosphate chiral ionic liquids were synthesized by the anion exchange reaction. The structures were characterized by IR, 1HNMR and structure optimization calculation. The results of studies on physicochemical properties show that they possess better thermal stability, solubility, bio-solubility and high conductivity. They can serve as effective reaction media as well as chiral catalysts. They are presently being investigated as dispersion agents in molecular imprinting ployer.

引用

页码：249 / 255

页数：7

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