电化学溶出法尺寸可控合成铜基氧还原反应催化剂:从纳米粒子到原子团簇和单原子（英文）

被引：4

作者：

李瑞 ^{[1
]}

徐劲松 ^{[2
]}

赵庆凯 ^{[1
]}

闫霞艳 ^{[1
]}

把静文 ^{[1
]}

宋雅琪 ^{[1
]}

曾荣光 ^{[1
]}

潘启发 ^{[2
]}

唐涛 ^{[1
]}

罗文华 ^{[1
]}

机构：

[1] Institute of Materials, China Academy of Engineering Physics

[2] Science and Technology on Surface Physics and Chemistry

来源：

Science China(Materials) | 2023年 / 66卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O643.36 [催化剂]; TB383.1 [];

学科分类号：

摘要：

从纳米尺度到亚纳米尺度甚至到原子尺度的非贵金属粒子的尺寸可控合成对阐明金属催化剂对氧还原反应催化的尺寸效应有重要意义.本文中,我们提出了一种电化学溶出策略,用于在硫掺杂的还原氧化石墨烯上自上而下制备铜纳米粒子、原子簇及单原子.在该方法中,首先电沉积获得铜纳米粒子(约8 nm),而后使用溶出伏安法,通过调控终止电位可控地将铜纳米粒子尺寸降低至原子簇尺度(约2 nm)和单原子尺度(<1 nm).对活性铜物种尺寸的有效调控使我们可以方便地从多尺度研究铜催化氧还原反应中的尺寸效应.结果表明,单原子铜表现出良好的氧还原反应催化性能,其半波电位为0.86 V,电子转移数为3.98,并具有长期稳定性,远优于其他大尺寸铜颗粒.这些研究结果为自上而下制备特定尺寸金属离子提供了新途径,将有利于尺寸可控氧还原电催化剂的未来设计.

引用

页码：1427 / 1434

页数：8

共 46 条

[31] InSitu Thermal Atomization To Convert Supported Nickel Nanoparticles into Surface-Bound Nickel Single-Atom Catalysts
Yang, Jian
Qiu, Zongyang
Zhao, Changming
Wei, Weichen
Chen, Wenxing
Li, Zhijun
Qu, Yunteng
Dong, Juncai
Luo, Jun
Li, Zhenyu
Wu, Yuen
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (43) : 14095 - 14100
[32] Direct transformation of bulk copper into copper single sites via emitting and trapping of atoms
Qu, Yunteng
Li, Zhijun
Chen, Wenxing
Lin, Yue
Yuan, Tongwei
Yang, Zhengkun
Zhao, Changming
Wang, Jing
Zhao, Chao
Wang, Xin
Zhou, Fangyao
Zhuang, Zhongbin
Wu, Yuen
Li, Yadong
[J]. NATURE CATALYSIS, 2018, 1 (10): : 781 - 786
[33] Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
Liu, Lichen
Corma, Avelino
[J]. CHEMICAL REVIEWS, 2018, 118 (10) : 4981 - 5079
[34] Boosting oxygen reduction catalysis with abundant copper single atom active sites
Li, Feng
Han, Gao-Feng
Noh, Hyuk-Jun
Kim, Seok-Jin
Lu, Yalin
Jeong, Hu Young
Fu, Zhengping
Baek, Jong-Beom
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2018, 11 (08) : 2263 - 2269
[35] Nitrogen and Sulfur Codoped Graphite Foam as a Self-Supported Metal-Free Electrocatalytic Electrode for Water Oxidation
Yu, Xiaowen
Zhang, Miao
Chen, Ji
Li, Yingru
Shi, Gaoquan
[J]. ADVANCED ENERGY MATERIALS, 2016, 6 (02)
[36] High-yield preparation of graphene oxide from small graphite flakes via an improved Hummers method with a simple purification process.[J].Ji Chen;Yingru Li;Liang Huang;Chun Li;Gaoquan Shi.Carbon.2015,
[37] Challenges in applying highly active Pt-based nanostructured catalysts for oxygen reduction reactions to fuel cell vehicles
Kodama, Kensaku
Nagai, Tomoyuki
Kuwaki, Akira
Jinnouchi, Ryosuke
Morimoto, Yu
[J]. NATURE NANOTECHNOLOGY, 2021, 16 (02) : 140 - 147
[38] Advanced Platinum-Based Oxygen Reduction Electrocatalysts for Fuel Cells
Huang, Lei
Zaman, Shahid
Tian, Xinlong
Wang, Zhitong
Fang, Wensheng
Xia, Bao Yu
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2021, 54 (02) : 311 - 322
[39] Transition Metal and Metal-N<sub>x</sub> Codoped MOF-Derived Fenton-Like Catalysts: A Comparative Study on Single Atoms and Nanoparticles..[J].Gao Yun;Yang Chengdong;Zhou Mi;He Chao;Cao Sujiao;Long Yanping;Li Shuang;Lin Yi;Zhu Puxin;Cheng Chong.Small (Weinheim an der Bergstrasse; Germany).2020, 50
[40] Synthetic strategies of supported atomic clusters for heterogeneous catalysis
Rong, Hongpan
Ji, Shufang
Zhang, Jiatao
Wang, Dingsheng
Li, Yadong
[J]. NATURE COMMUNICATIONS, 2020, 11 (01)

← 1 2 3 4 5 →