Iron-catalyzed transformations of diazo compounds

被引：0

作者：

ShouFei Zhu ^{[1
,2
]}

QiLin Zhou ^{[1
,2
]}

机构：

[1] State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University

[2] Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)

来源：

National Science Review | 2014年 / 1卷 / 04期

关键词：

iron; catalysis; diazo compounds; synthesis;

D O I：

暂无

中图分类号：

O643.36 [催化剂];

学科分类号：

081705 ;

摘要：

Although iron-promoted diazo transformations were only discovered during the 1990s,iron can undergo facile changes in its oxidation state and possesses distinct Lewis acid character,and these properties have aforded iron a privileged position as a catalyst in the transformations of diazo compounds.In this review,we have provided an overview of the iron-catalyzed diazo transformation reactions reported in the literature by the end of 2013 with the aim of stimulating further interest in this area of research.

引用

页码：580 / 603

页数：24

共 29 条

[1]

Recent advances in the iron-catalyzed cycloaddition reactions[J]. WANG ChunXiang ＆ WAN BoShun Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China.Chinese Science Bulletin. 2012(19)

[2]

Enzyme Promiscuity: Using a P450 Enzyme as a Carbene Transfer Catalyst[J] . Gheorghe‐Doru Roiban,Manfred T. Reetz.Angew. Chem. Int. Ed. . 2013 (21)

[3]

Reactions of Iron Carbenes with α,β‐Unsaturated Esters by Using an Umpolung Approach: Mechanism and Applications[J] . Peng Wang,Lin Ling,Sai‐Hu Liao,Jian‐Bo Zhu,Sunewang R. Wang,Yu‐Xue Li,Yong Tang.Chem. Eur. J. . 2013 (21)

[4]

One Pot, Two Phases: Iron‐Catalyzed Cyclopropanation with In?Situ Generated Diazomethane[J] . Johannes Kaschel,Tobias F. Schneider,Daniel B. Werz.Angew. Chem. Int. Ed. . 2012 (29)

[5]

Catalytic Activation of Diazo Compounds Using Electron‐Rich, Defined Iron Complexes for Carbene‐Transfer Reactions[J] . Michael S.Holzwarth,IsabelAlt,BerndPlietker.Angew. Chem. Int. Ed. . 2012 (22)

[6] Update [J].

Zeitschrift für Rheumatologie, 2012, 71 (9) :730-731

[7]

Chemical reactivity of 6-diazo-5-oxo- l -norleucine （DON） catalyzed by metalloporphyrins （Fe,Ru）[J] . Paul Le Maux,Irène Nicolas,Soizic Chevance,Gérard Simonneaux.Tetrahedron . 2010 (25)

[8]

Iron‐Catalyzed Cyclopropanation with Trifluoroethylamine Hydrochloride and Olefins in Aqueous Media: In?Situ Generation of Trifluoromethyl Diazomethane[J] . Angewandte Chemie International Edition . 2010 (5)

[9] Asymmetric intermolecular cyclopropanation of alkenes by diazoketones catalyzed by Halterman iron porphyrins [J].

Nicolas, Irene ;

Roisnel, Thierry ;

Le Maux, Paul ;

Simonneaux, Gerard .

TETRAHEDRON LETTERS, 2009, 50 (36) :5149-5151

[10]

Cobalt and iron complexes of chiral C 1 - and C 2 -terpyridines: Synthesis, characterization and use in catalytic asymmetric cyclopropanation of styrenes[J] . Chi-Tung Yeung,Kiu-Chor Sham,Wing-Sze Lee,Wing-Tak Wong,Wai-Yeung Wong,Hoi-Lun Kwong.Inorganica Chimica Acta . 2009 (9)

← 1 2 3 →