Influence of additive element on surface oxide film of A356 alloy

被引:0
作者
欧阳志英
梁红玉
毛协民
红梅
机构
[1] School of Material Science and Engineering Shanghai University
[2] Shanghai 200072
[3] China
关键词
A356 aluminum alloy; rare earth elements; surface oxide film; gas porosity; strontium;
D O I
暂无
中图分类号
TG174 [腐蚀的控制与防护];
学科分类号
080503 ;
摘要
The influences of RE-modification and Sr-modification on the hydrogen content and surface oxide film of A356 aluminum alloy melt were investigated. The hydrogen content of the melt was measured by reduce pressure test. The phases in the surface oxide film were analyzed by X-ray diffractometry (XRD), and the morphology of the surface oxide film was observed by scanning electronic microscopy (SEM). The results show that RE-modification reduces the hydrogen content of A356 aluminum alloy greatly. Contrarily, Sr-modification increases the hydrogen content remarkably. After being treated with RE, a large number of LaAl11O18 consisting of Al2O3 and La2O3, are generated in the surface oxide film of A356 alloy. The surface oxide film of Sr-modification is almost composed of Al2SrO4. According to the results of SEM, the surface oxide film of Sr-modification is very easy to crack, destroy the continuity and compactness of surface oxide film, accelerate the vapor diffusing into the melt, consequently, increase the hydrogen content of A356 alloy melt significantly. But RE-modification makes the surface oxide film compact, and restrains the aluminum exposed to water, so reduces the hydrogen content of A356 alloy melt.
引用
收藏
页码:1425 / 1428
页数:4
相关论文
共 2 条
  • [1] Effects of Sr-modification and melt cleanliness on melt hydrogen absorption of 319 aluminium alloy
    Shabestari, SG
    Miresmaeili, SM
    Boutorabi, SMA
    [J]. JOURNAL OF MATERIALS SCIENCE, 2003, 38 (09) : 1901 - 1907
  • [2] Influence of oxides on porosity formation in Sr-treated Al-Si casting alloys
    Liu, L
    Samuel, AM
    Samuel, FH
    Doty, HW
    Valtierra, S
    [J]. JOURNAL OF MATERIALS SCIENCE, 2003, 38 (06) : 1255 - 1267