Synthesis of Novel Polymer-Bonded Water-Soluble Metal Porphyrins

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关键词
polymer-bonded metal porphyrin; water-soluble porphyrin; synthesis;
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中图分类号
O627.8 [第Ⅷ族元素有机化合物];
学科分类号
070303 ; 081704 ;
摘要
The reaction of 5, 10, 15, 20-tetra-(4-pyridyl) porphyrin 1 with triruthenium dodecacarbonyl [Ru3 (CO)12], zinc (II) acetate, copper(II) acetate, cobalt (II) acetate afforded complexes 2a-2d respectively.Treatment of 2a-2d with Merrifield’s peptide resin obtained 3a-3d. The compounds 3a-3d reacted with methyl iodide respectively gave 4a-4d. New complexes 4a-4d have been identified hy IR, UV-visible spectra, and AES.
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页码:375 / 376
页数:2
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