A CLUSTER COMPOUND WITH DI-ENDOXYGEN LIGANDS——THE CRYSTAL AND MOLECULAR STRUCTURE OF [Fe（MOS4O）2][N（C2H5）4]3

被引：0

作者：

王凤山

樊玉国

吕品喆

徐吉庆

刘喜生

机构：

[1] Department of Chemistry

[2] Changchun

[3] Jilin University

[4] Changohun

[5] Institute of Theoretical Chemistry

来源：

Science China Chemistry | 1986年 / 06期

关键词：

Fe; Mo; THE CRYSTAL AND MOLECULAR STRUCTURE OF; MOS4O; C2H5; A CLUSTER COMPOUND WITH DI-ENDOXYGEN LIGANDS;

D O I：

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中图分类号：

学科分类号：

摘要：

[Fe（MoSO）] [N（CH）]cluster compound with di-end-oxygen ligands has been prepared and characterized by the X-ray diffraction method. The compound crystallizes in a monoclinic space group P2/n with lattice parameters a=13.019（4）, b=16.959（5）, c=18.234（5）, β=97.34（2）(°), Z=4. The final agreement factors are R=0.0740, Rw=0.0598. The terminal bond length, Mo-Sand bridged one, MO-Sfor the compound are much longer than the counterpart without end-oxygen ligand. It possibly suggests that low valence of molybdenum and smaller electronegativity of sulphur than oxygen lead to the charge transfer as S→Mo→O.

引用

页码：571 / 578

页数：8

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