Structure and hydrogen storage characteristics of as-spun Mg-Y-Ni-Cu alloys

被引:0
作者
Yanghuan Zhang [1 ,2 ]
Pengpeng Wang [1 ,2 ]
Zhonghui Hou [1 ,2 ]
Zeming Yuan [1 ,2 ]
Yan Qi [2 ]
Shihai Guo [2 ]
机构
[1] Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources,Inner Mongolia University of Science and Technology
[2] Department of Functional Material Research,Central Iron and Steel Research Institute
关键词
Mg-Ni-based alloy; Thermodynamics; Activation energy; Melt spinning; Hydrogen storage kinetics;
D O I
暂无
中图分类号
TG139.7 []; TG146.22 [];
学科分类号
080502 ;
摘要
Experimental alloys with compositions of Mg;Y;Ni;Cu(x=0,1,3,5,7)have been successfully prepared through melt spinning method.The phase compositions and microstructures were measured by X-Ray diffraction(XRD)and high-resolution transmission electron microscopy(HRTEM).The de-/hydrogenation properties were measured by utilizing Sievert apparatus,differential scanning calorimetry(DSC)and thermal gravimetric analyzer(TGA)connected with a H;detector.The Arrhenius and Kissinger methods were adopted to calculate their dehydrogenation activation energies.The results show that hydrogen absorption kinetics of the alloys notably decline while their hydrogen desorption kinetics conspicuously improve with spinning rate increasing.The dehydrogenation activation energy markedly decreases with spinning rate increasing,which makes the hydrogen desorption kinetics improve.The thermodynamic parameters(H and S absolute values)clearly decrease with spinning rate increasing.The hydrogen absorption capacity exhibits different trends with spinning rate rising.Specifically,hydrogen absorption capacity increases at the beginning and declines later for Y;alloy,but that of Y;alloy always decreases with spinning rate growing.
引用
收藏
页码:1727 / 1734
页数:8
相关论文
共 2 条
[1]  
T.Grosdidier,J.J.Fundenberger,J.X.Zou,Y.C.Pan,X.Q.Zeng. Int.J.Hydrogen Energy . 2015
[2]  
T.Sadhasivam,M.Sterlin Leo Hudson,K.P.Sunita,B.Ashish,K.S.Milind,K.Gurunathan,O.N.Srivastava. Int.J.Hydrogen Energy . 2013