Selective oxidation of biomass derived 5-hydroxymethylfurfural to 2,5-diformylfuran using sodium nitrite

被引：0
|
作者：
Xianxiang Liu [1 ]
Hui Ding [1 ]
Qiong Xu [1 ]
Wenzhou Zhong [1 ]
Dulin Yin [1 ]
Shengpei Su [1 ]
机构：
[1] National & Local Joint Engineering Laboratory for New Petro-Chemical Materials and Fine Utilization of Resources, Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education of China), College of Chemistry and Chemic
来源：
Journal of Energy Chemistry | 2016年 / 01期
基金：
中国国家自然科学基金;
关键词：
5-hydroxymethylfurfural; 2,5-diformylfuran; Sodium nitrite; Oxidation; Renewable resource;
D O I：
暂无
中图分类号：
O621.25 [];
学科分类号：
摘要：
A mild and simple process for the effective oxidation of 5-hydroxymethylfurfural（HMF） into 2,5-diformylfuran（DFF） has been developed using Na NO;as the oxidant. Some important reaction parameters were investigated to optimize the oxidation of HMF into DFF. It was found that the reaction solvent was very crucial for this reaction. Trifluoroacetic acid was the best solvent for the oxidation of HMF into DFF by Na NO;.Under the optimal reaction condition, almost quantitative HMF conversion and high DFF yield of 90.4% were obtained after 1 h at room temperature.
引用
收藏
页码：117 / 121
页数：5
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