Catalytic Performance of CeO2/ZnO Nanocatalysts on the Oxidative Coupling of Methane with Carbon Dioxide and their Fractal Features

被引:1
作者
Blun Yang
机构
[1] Department of Chemical Engineering
[2] Xian Jiaotong University
[3] Xi’an 710049
[4] Chin
关键词
methane; carbon dioxide; oxidative coupling; CeO2/ZnO nanocatalysts; fractal dimension;
D O I
暂无
中图分类号
O643.3 [催化];
学科分类号
081705 ;
摘要
CeO2/ZnO nanocatalysts were prepared from the coupling route of homogeneous precipita-tion with microemulsion and the impregnation method. The catalytic performance of these two kinds of catalysts on the oxidative coupling of methane with carbon dioxide was tested and compared; the frac-tal behavior of the nanocatalysts was analyzed using fractal theory. The CeO2/ZnO nanocatalysts had much higher activity than the catalysts prepared by impregnation method. There was no regular relation-ship between the average size of CeO2/ZnO nanocatalysts and their catalytic performance; however, the conversion of methane increased with the increase of the fractal dimension of CeO2/ZnO nanocatalysts.
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页码:167 / 171 +4
页数:6
相关论文
共 9 条
  • [1] Huo C,Ren X,Zong Y et al. Petrochemical Technology . 1999
  • [2] He Y,Yang B,Cheng G. Materials Letters . 2003
  • [3] Asami K,Fujita T,Kusakabe K. Applied Catalysis A General . 1995
  • [4] Wang Y,Takahashi Y,Ohtsuka Y. Applied Catalysis A General . 1998
  • [5] Thurston T R,Wilcoxon J P. Journal of Physical Chemistry B . 1999
  • [6] Larraz R. Chemical Engineering . 2002
  • [7] Wang H,Wang J,Xiao W. Powder Technology . 2000
  • [8] Coppens M. Colloids and Surfaces A: Physicochemicaland Engineering Aspects . 2001
  • [9] Pfeifer P,Avnir D. The Journal of Chemical Physics . 1983