Syntheses,Crystal Structures and Thermal and Optical Properties of Two Organic Templated Gallium Antimony Sulfides

被引：0
|
作者：
孔德年 [1 ]
冯美玲 [1 ]
叶冬 [1 ]
黄小荥 [1 ]
机构：
[1] State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences
来源：
结构化学 | 2010年 / 29卷 / 06期
关键词：
gallium; antimony; sulfide; in situ reaction; crystal structure;
D O I：
10.14102/j.cnki.0254-5861.2010.06.002
中图分类号：
O614.37 [镓副族（ⅢA族金属元素）];
学科分类号：
070301 ; 081704 ;
摘要：
Two new gallium antimony sulfides,[enH2][Ga2Sb2S7]·en(1) and [puH]2[Ga2Sb2S7](2)(en = ethylenediamine,pu = propyleneurea),have been solvothermally synthesized.In the pre-paration of compound 2,the protonated propyleneurea cation as counterion and template was in situ synthesized by the reaction of 1,3-diaminopropane with CO2 in pyridine.Both structures contain a two-dimensional network composed of novel heterometallic clusters of {Ga2Sb2S9} as the second-dary building unit.The thermal and optical properties of compounds 1 and 2 were characterized by TGA and UV-Vis,respectively.
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收藏
页码：905 / 913
页数：9
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