Effect of Heat-treatment on Crystalline Phase and UV Absorption of 60CeO2-40TiO2 Thin Films by Magnetron Sputtering

被引:0
作者
倪佳苗 [1 ,2 ,3 ]
赵修建 [1 ]
机构
[1] State Key Laboratory of Silicate Materials for Architectures (Wuhan University of Technology)
[2] Department ofArchitecture and Material Engineering,Hubei University of Education
[3] National Engineering Laboratory for FiberOptic Sensing Technology,Wuhan University of Technology
基金
中央高校基本科研业务费专项资金资助; 中国博士后科学基金; 中国国家自然科学基金;
关键词
CeO2-TiO2 thin films; UV absorption; CeO2 crystallite phase; radio frequency magnetron sputtering;
D O I
暂无
中图分类号
TB383.2 [];
学科分类号
070205 ; 080501 ; 1406 ;
摘要
60CeO2-40TiO2 thin films were deposited on soda-lime silicate glass substrates by R.F. magnetron sputtering. The effects of heat-treatment on the UV-absorption of the thin films were studied on the 60CeO2-40TiO2 thin film with the largest UV cut-off wavelength. The sample films with CeO2:TiO2=60:40 were heated at 773 K, 873 K, 973 K for 30 min. These films are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy and spectrometer (XPS). XRD analysis proves that the addition of TiO2 to CeO2 changed the crystalline state of CeO2. But the UV absorption effect of CeO2-TiO2 films with CeO2 crystallite phase is inferior to that of the amorphous phase CeO2-TiO2 films. XPS analysis also indicates that the amorphous phase CeO2-TiO2 films have the most Ce3+ content in these films. Amorphous phase and crystalline phase of the CeO2-TiO2 films have different effects on UV absorption of the thin films.
引用
收藏
页码:881 / 885
页数:5
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