Click synthesis and dye extraction properties of novel thiacalix[4]arene derivatives with triazolyl and hydrogen bonding groups

被引：0
|
作者：
Hong-Yu Guo [1 ]
Fa-Fu Yang [1 ,2 ]
Zi-Yu Jiao [2 ]
Jian-Rong Lin [1 ]
机构：
[1] College of Chemistry and Chemical Engineering,Fujian Normal University
[2] Fujian Key Laboratory of Polymer Materials,Fujian Normal University
来源：
ChineseChemicalLetters | 2013年 / 24卷 / 06期
基金：
中国国家自然科学基金;
关键词：
Thiacalix[4]arene; Synthesis; Click chemistry; Dye extraction;
D O I：
暂无
中图分类号：
O626 [杂环化合物];
学科分类号：
摘要：
Using a click reaction between alkynylthiacalix[4]arene and ethyl 2-azidoacetate followed by an ammonolysis with ethanolamine,leucinol and hydrazine hydrate,respectively,three novel thiacalix [4]arene derivatives 4,5 and 6 with triazolyl and hydrogen bonding groups(NH and OH) were synthesized in high yields.They exhibited excellent extraction capability for six anionic and cationic dyes.The flexible cavity,π-triazole rings and hydrogen bonding groups all play crucial roles in dye complexation.
引用
收藏
页码：450 / 452
页数：3
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