Preparation and optical characteristics of ZnO films by chelating sol-gel method

被引:0
作者
YANG Lirong JIN Zhengguo BU Shaojing SUN Hingchun and CHENG Zhijie Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education Materials School Tianjin University Tianjin China [300072 ]
机构
关键词
ZnO thin films; preparation and optical properties; chelating sol-gel method; citric acid;
D O I
暂无
中图分类号
TB43 [薄膜技术];
学科分类号
0805 ;
摘要
<正> The effect of different annealing temperatures on the structure, morphology, and optical properties of ZnO thin films prepared by the chelating sol-gel method was investigated. Zinc-oxide thin fdms were coated on quartz glass substrates by dip coating. Zinc nitrate, absolute ethanol, and citric acid were used as precursor, solvent, and chelating agent, respectively. The results show that ZnO films derived from zinc-citrate have lower crystallization temperature (below 400℃), and that the crystal structure is wurtzite. The films, treated over 500℃, consist of nano-particles and show to be porous at 600C. The particle size of the film increases with the increase of the annealing temperature. The largest particle size is 60 nm at 600℃. The optical transmittances related to the annealing temperatures become 90% higher in the visible range. The film shows a starting absorption at 380nm, and the optical band-gap of the thin film (fired at 500℃) is 3.25 eV and close to the intrinsic band-gap of ZnO (3.2 e
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页码:214 / 219
页数:6
相关论文
共 2 条
[1]  
Application of sol-gel derived films for ZnO/n-Si junction solar cells. Balk D.G. and Cho S.M. Thin Solid films . 1999
[2]  
Zinc oxide films prepared by sol-gel spin-coating. Natsume Y. and Sakata H. Thin Solid films . 2000