Crystal Structure and Magnetic Property of a Two-dimensional Manganese Compound [Mn（PhCOO）2（4,4'-bipyridine）]n

被引：0

作者：

陈惠 ^{[1
]}

王文国 ^{[1
]}

马成丙 ^{[1
]}

陈昌能 ^{[1
]}

刘秋田 ^{[1
]}

廖代正 ^{[2
]}

李立存 ^{[2
]}

机构：

[1] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences 2. Department of Chemistry, Nankai University

来源：

Chinese Journal of Structural Chemistry | 2007年 / 06期

关键词：

manganese; crystal structure; magnetic property;

D O I：

10.14102/j.cnki.0254-5861.2007.06.013

中图分类号：

O627.7 [第Ⅶ族元素有机化合物（卤素除外）];

学科分类号：

070303 ; 081704 ;

摘要：

A new two-dimensional polymeric manganese compound [Mn(PhCOO)2(4,4’-bi-pyridine)]n 1 has been prepared and structurally characterized by X-ray diffraction. The complex crystallizes in space group Pbcn with a = 18.7158(2), b = 11.6919(3), c = 9.4799(2) , V = 2074.42(7) 3, Z = 4, Mr = 453.34, Dc = 1.452 g/cm3, μ = 0.670 mm-1 and F(000) = 932. The final refinement gave R = 0.0458 and wR = 0.1439 for 1358 observed reflections with I > 2σ(I). The complex consists of repeating units of Mn(PhCOO)2(4,4’-bipyridine). Each Mn center is six-coordinated by four carboxylate O atoms of four benzoate anions and two pyridyl N atoms from bipy ligands to furnish a slightly distorted octahedral geometry. The two adjacent Mn atoms are connected by a pair of μ1,3-carboxylate groups to form infinite chains, which are further interlinked by bipy to complete a 2D grid network. The magnetic property of the polymeric complex has also been investigated.

引用

页码：687 / 690

页数：4

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