Crystal Structure of Phenol,2-[4(S)-4-Dihydro-4-benzyl-2-ozazolinyl]

被引：0
|
作者：
罗梅 [1 ]
周仕明 [2 ]
张家海 [2 ]
庞文民 [3 ]
尹浩 [2 ]
胡克良 [2 ]
机构：
[1] Hefei University of Technology,Department of Chemical Engineering
[2] University of Science and Technology,Department of Chemistry (Hefei)
[3] University of Science and Technology,Department of Chemistry (Hefei)
来源：
结构化学 | 2010年 / 29卷 / 06期
关键词：
oxazoline; phenol; 2-[4(S)-4; 5-dihydro-4-phenyl-2-ozazolinyl; (C15H13NO2); crystal structure;
D O I：
10.14102/j.cnki.0254-5861.2010.06.019
中图分类号：
O621.2 [有机化合物性质];
学科分类号：
070303 ; 081704 ;
摘要：
The compound phenol,2-[4(S)-4,5-dihydro-4-phenyl-2-ozazolinyl(1,C15H13NO2) was synthesized with a simple,one step method free of water and air.It was obtained in a moderate yield from the reaction of 2-hydroxybenzonitrile with optically active amino alcohol in chloroben-zene under dry,anaerobic conditions.It belongs to the orthorhombic system,space group P212121 with a = 5.786(5),b = 10.730(5),c = 19.722(5),C15H13NO2,Mr = 239.26,V = 1224.4(12)3,Z = 4 and Dc = 1.298 mg/m3.The final R = 0.0324 for 1627 observed reflections with Ⅰ > 2σ(Ⅰ) and Rw = 0.0826 for all data.The structure of compound 1 was determined by X-ray diffraction,NMR and HRMS.
引用
收藏
页码：947 / 949
页数：3
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