共 2 条
- [1] J.M.William,et al. Science . 1991
- [2] U.A.Geiser,J.A.Schlueter,H.H.Wang,et al. Journal of the American Chemical Society . 1996
Synthesis, Structure and Conductivity of the New Charge-transfer Salt （ET）2（CH2=CH-CH2-SO3）·H2O
被引：0
作者：
Zhi LIU1
机构：
基金：
中国国家自然科学基金;
关键词：
ET;
electro-oxidation;
crystal structure;
conductivity;
D O I：
暂无
中图分类号：
O621.25 [];
学科分类号：
070303 ;
081704 ;
摘要：
Electro-oxidation of 3,4,3, 4-bis(ethylenedithio)-2,2,5,5-tetrathiafulvalen (abbr. ET) in the presence of allylsulfonate affords a new charge-transfer salt (ET)2(CH2=CH-CH2-SO3)H2O. The single crystal structure of the title compound is determined to be in orthorhombic crystal system, Pma2 space group. This salt is a semiconductor and its room-temperature conductivity is 0.0489Ω-1m-1.
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页码：433 / 436
页数：4
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