Synthesis and X-ray Crystal Structure of a New Molecular Clip

被引：0
|
作者：
佘能芳
高蒙
王帅
吴安心
机构：
[1] Key Laboratory of Pesticide & Chemical Biology Ministry of Education College of Chemistry Central China Normal University
[2] Wuhan 430079 China
[3] Key Laboratory of Pesticide & Chemical Biology Ministry of Education College of Chemistry Central China Normal University
来源：
Chinese Journal of Structural Chemistry | 2008年 / 07期
基金：
中国国家自然科学基金;
关键词：
molecular clip; X-ray crystal structure; boat conformation;
D O I：
10.14102/j.cnki.0254-5861.2008.07.005
中图分类号：
O76 [晶体结构];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The synthesis and X-ray crystal structure of a new molecular clip 2 was reported. It (C24H24N4O2, Mr = 400.47) crystallizes in the space group C2/c with a = 15.587(2), b = 8.5805(12), c = 15.259(2) , β = 102.448(3)°, V = 1992.9 (5) 3, Z = 4, Dc = 1.335 g/cm3, μ = 0.087 mm-1 and F(000) = 848. It remains monomeric in the crystal and a tape-like structure is formed in the crystal structure of molecular clip. The most unusual structural feature of 2 is the boat conformation of its cyclohexyl ring imposed by the ring fusion at C(9)-C(9a).
引用
收藏
页码：777 / 780
页数：4
相关论文
共 50 条
  • [11] THE X-RAY CRYSTAL AND MOLECULAR-STRUCTURE OF GLECHOMAFURAN
    KORP, JD
    BERNAL, I
    JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH, 1985, 15 (02): : 191 - 199
  • [12] AN X-RAY DETERMINATION OF CRYSTAL AND MOLECULAR STRUCTURE OF PERCHLOROFULVALENE
    WHEATLEY, PJ
    JOURNAL OF THE CHEMICAL SOCIETY, 1961, (NOV): : 4936 - &
  • [13] MOLECULAR AND CRYSTAL-STRUCTURE OF IODIXANOL, A NEW X-RAY CONTRAST AGENT
    TONNESSEN, LE
    PEDERSEN, BF
    KLAVENESS, J
    ACTA CHEMICA SCANDINAVICA, 1995, 49 (06): : 433 - 440
  • [14] Synthesis and X-ray crystal structure determination of new zwitterionic complexes of titanocene
    Burlakov, VV
    Arndt, P
    Baumann, W
    Spannenberg, A
    Rosenthal, U
    Letov, AV
    Lyssenko, KA
    Korlyukov, AA
    Strunkina, LI
    Minacheva, MK
    Shur, VB
    ORGANOMETALLICS, 2001, 20 (19) : 4072 - 4079
  • [15] Synthesis and X-ray crystal structure of a thymidine derivative
    Kim, SJ
    Lee, JY
    Ko, KH
    Kim, BH
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1998, 19 (08) : 816 - 817
  • [16] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF GERMAIMINES
    MELLER, A
    OSSIG, G
    MARINGGELE, W
    STALKE, D
    HERBSTIRMER, R
    FREITAG, S
    SHELDRICK, GM
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (16) : 1123 - 1124
  • [17] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF TETRAPHENYLDIARSETENE
    SENNYEY, G
    MATHEY, F
    FISCHER, J
    MITSCHLER, A
    ORGANOMETALLICS, 1983, 2 (02) : 298 - 304
  • [18] Synthesis and X-ray crystal structure of decamethylrhodocenium hexafluorophosphate
    Buchholz, D
    Zsolnai, L
    Huttner, G
    Astruc, D
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 593 : 494 - 496
  • [19] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A STANNAIMINE
    OSSIG, G
    MELLER, A
    FREITAG, S
    HERBSTIRMER, R
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (06) : 497 - 499
  • [20] Synthesis and X-ray crystal structure of a cyclic hemiorthoester
    Austin, Kerrie A. B.
    Banwell, Martin G.
    Willis, Anthony C.
    ARKIVOC, 2006, : 1 - 7
12345