Synthesis and X-ray Crystal Structure of a New Molecular Clip

被引：0

作者：

佘能芳

高蒙

王帅

吴安心

机构：

[1] Key Laboratory of Pesticide & Chemical Biology Ministry of Education College of Chemistry Central China Normal University

[2] Wuhan 430079 China

[3] Key Laboratory of Pesticide & Chemical Biology Ministry of Education College of Chemistry Central China Normal University

来源：

Chinese Journal of Structural Chemistry | 2008年 / 07期

基金：

中国国家自然科学基金;

关键词：

molecular clip; X-ray crystal structure; boat conformation;

D O I：

10.14102/j.cnki.0254-5861.2008.07.005

中图分类号：

O76 [晶体结构];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The synthesis and X-ray crystal structure of a new molecular clip 2 was reported. It (C24H24N4O2, Mr = 400.47) crystallizes in the space group C2/c with a = 15.587(2), b = 8.5805(12), c = 15.259(2) , β = 102.448(3)°, V = 1992.9 (5) 3, Z = 4, Dc = 1.335 g/cm3, μ = 0.087 mm-1 and F(000) = 848. It remains monomeric in the crystal and a tape-like structure is formed in the crystal structure of molecular clip. The most unusual structural feature of 2 is the boat conformation of its cyclohexyl ring imposed by the ring fusion at C(9)-C(9a).

引用

页码：777 / 780

页数：4

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