Synthesis and Structure of a New Dinuclear Molybdenum（Ⅰ）Compound with Cyclohexanthiolate Ligand,[Mo2(SC6H112（CO）8]

被引：0
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作者：
ZHOU Zhang-Feng ZHUANG Bo-Tao WEI QiangPENG Sai-Qun WU Ke-Chen LIN Chen-Sheng(State Key Laboratory of Structural Chemistry
机构：
来源：
结构化学 | 2002年 / 06期
关键词：
molybdenum( I )-compound; synthesis; structure;
D O I：
10.14102/j.cnki.0254-5861.2002.06.010
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
摘要：
Molybdenum( I )-compound [Mo2(SC6H11)2(CO)8] 1, crystallizes in monoclinic, space group P21/c with a = 9.5863(9), b = 9.4469(9), c = 13.869(1) A, β = 99.697(2)°, V= 1238.1(2) A3, Z = 2,DC= 1.734 g/cm3, μ = 12.23 cm-1 and F(000) = 644. The finalR = 0.0455 and wR = 0.1159 for 1590 observed reflections with I> 2σ(I). 1 possesses a rhombic bimetallic core MoS2Mo with the Mo-Mo bond length of 2.975(1) and Mo-S of 2.485(2) A.
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页码：626 / 628
页数：3
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