Hydrothermal Synthesis,Crystal Structure and Properties of a New Binuclear Nickel(Ⅲ) Complex with 3-(Pyridin-2-yl)-1,2,4-triazole

被引：1

作者：

李昶红

李玉林

李薇

匡云飞

机构：

[1] School of Chemistry and Materials Science,Hengyang Normal University

[2] School of Materials and Chemical Engineering,Hunan Institute of Technology

来源：

Chinese Journal of Structural Chemistry | 2021年 / 40卷 / 03期

关键词：

D O I：

10.14102/j.cnki.0254-5861.2011-2931

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

A new binuclear nickel(II) complex Ni(HPT)(HO)(1) has been hydrothermally synthesized with nickel hydroxide,3,4-pyridine dicarboxylic acid and 3-(pyridin-2-yl)-1,2,4-triazole (HPT) in the mixed solution (the volume ratio of methanol and water is 1:4).It crystallizes in tetragonal space group P4/n,with a=20.844(1),b=20.844(1),c=7.2463(7)?,V=3148.2(5)?~3,D=1.587 g/cm~3,Z=4,μ(Mo Ka)=1.257,F(000)=1544,the final GOOF=1.043,R=0.0437 and w R=0.1297.The crystal structure shows that the whole molecule consists of two nickel ions which are bridged by fourμ-η~1:η~0-3-(pyridin-2-yl)-1,2,4-triazole anions.The coordination environment of Ni(II) ion is Ni N,giving a distorted octahedral geometry.The thermal stability and fluorescent and magnetic properties of the complex were investigated.

引用

页码：363 / 368

页数：6

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