The First Example of Inorganic-organic Compound Involving the Largest Vanadium Cluster of [V34O82]10-: Hydrothermal Synthesis and Characterization of a One-dimensional Chain of {[NiC16H36N4]5[V34O82]}n

被引：0

作者：

欧光川 ^{[1
]}

袁先友 ^{[1
]}

李治章 ^{[1
]}

机构：

[1] Department of Biology and Chemistry,Hunan University of Science and Engineering

来源：

Chinese Journal of Structural Chemistry | 2013年 / 03期

关键词：

hydrothermal synthesis; macrocyclic nickel(Ⅱ) complexes; vanadium cluster;

D O I：

10.14102/j.cnki.0254-5861.2013.03.008

中图分类号：

O611.4 [无机合成化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound, [NiL]5[V34O82·8H2O (1, L=5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane), has been synthesized under hydrothermal conditions and structurally characterized by EA, IR, XPS, TG and single-crystal X-ray diffraction. It crystallizes in the monoclinic system, space group C2/c with a=33.061(4), b=15.3457(17), c=33.902(4), β=101.930(2)°, Mr=4904.08, V=16828(3)3 , Z=4, Dc=1.936 g/cm3 , F(000)=9832, μ=2.425 mm-1 , the final R=0.0402 and wR=0.0969. The mixed valence vanadium clusters of [V34O82]10- bridges [NiL]2+ to form a one-dimensional chain in 1. To the best of our knowledge, the title complex is the first example of organic-inorganic hybrid material involving the largest vanadium cluster of [V34O82]10-.

引用

页码：375 / 380

页数：6