STUDIES ON THE ACTIVITY COEFFICIENTS OF NON-ELECTROLYES IN AQUEOUS SALT SOLUTIONS Ⅲ. THR EFFECTS OF SALTS OF FATTY ACIDS ON THE SOLUBILITIES OF CAPROIC ACID IN WATER

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作者
YIN HENG CHENG
HUANG TZU-CHING and YANG WEN-CHEH (Department of Chemistry
Peking Univereity)
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OC; STUDIES ON THE ACTIVITY COEFFICIENTS OF NON-ELECTROLYES IN AQUEOUS SALT SOLUTIONS; THR EFFECTS OF SALTS OF FATTY ACIDS ON THE SOLUBILITIES OF CAPROIC ACID IN WATER; ACID;
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<正> The solubilities of caproic acid in aqueous solutions of sodium salts of fivefatty acids (C1 to C5) have been measured at 25℃. All these salts increase thesolubilities of caproic acid. The reason for salting-in is due to partial displacement of the salt by thecaproic acid producing a new acid. But the new acid may distribute itself betweenthe aqueous salt, solution phase and the caproic acid phase thus rendering the actualsolubilities less than the calculated values.
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页码:342 / 344
页数:3
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