由MOPIP配体构筑的两种金属配合物的合成、表征及晶体结构(英文)

被引:6
作者
黄艳菊 [1 ,2 ]
倪良 [1 ]
杜刚 [3 ]
崔运成 [4 ]
张文莉 [1 ]
王蕾 [1 ]
郝向荣 [2 ]
机构
[1] 江苏大学化学化工学院
[2] 通化师范学院化学系
[3] 通化市第一中学
[4] 吉林师范大学化学学院
关键词
2-(4-甲氧基)-1氢-咪唑[4,5-f][1,10]邻菲咯啉; 锰(Ⅱ); 镉(Ⅱ);
D O I
暂无
中图分类号
O641.4 [络合物化学(配位化学)];
学科分类号
070304 ; 081704 ;
摘要
采用水热法由2种不同金属盐和MOPIP(MOPIP=2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline)配体合成了2种新型零维配合物[Cd(MOPIP)3(H2O)9]4n(1)和[Mn(MOPIP)3(H2O)6]2n(2),并对其进行了元素分析、红外光谱表征、热失重和X射线单晶衍射测定。结果表明,每个金属中心离子与来自3个不同MOPIP分子上的6个氮原子进行配位,形成畸变的八面体构型。
引用
收藏
页码:1269 / 1273
页数:5
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