Crystal Structure and Characterization of a Binuclear Cd(Ⅱ) Quaternary Coordination Complex [Cd2(phen)2Q2(BP)]n(phen=1,10-Phenanthroline,BP = Biphenyl-4,4'-dicarboxylic acid,Q=8-Hydroxyquinoline Anion)

被引：2

作者：

王家军 ^{[1
]}

崔运成 ^{[1
]}

高广刚 ^{[1
]}

王仁章 ^{[2
]}

刘博 ^{[1
]}

王小美 ^{[1
]}

机构：

[1] Chemistry Department of Jilin Normal University

[2] Chemistry and Bioengineering Department of Sanming College

来源：

结构化学 | 2008年 / 09期

关键词：

phen; 8-hydroxyquinoline; cadmium(Ⅱ) complex; single-crystal structure; TG;

D O I：

10.14102/j.cnki.0254-5861.2008.09.014

中图分类号：

O627.23 [锌族金属有机化合物];

学科分类号：

070303 ; 081704 ;

摘要：

The structure of a binuclear cadmium(Ⅱ) quaternary complex,[Cd2(phen)2-Q2(BP)]n 1(phen = 1,10-phenanthroline,BP = biphenyl-4,4’-dicarboxylic acid,Q = 8-hydroxy-quinoline-anion),has been determined by X-ray crystallography and characterized by elemental analysis,IR spectrum and thermogravimetric analysis.It crystallizes in the monoclinic system,space group P21/n with a = 13.1906(18),b = 10.9623(15),c = 16.947(2) ,β = 111.3430(10)°,V = 2282.5(5) 3,Z = 4,Mr = 556.85,Dc = 1.620 g/cm3,F(000) = 1116,μ = 0.994 mm-1 and S = 1.056.In the structure,1D chains are connected via biphenyl-4,4’-dicarboxylic acid,8-hydroxy quinoline anion and binuclear cadmium atoms into an infinite 1-D molecular chain architecture.Via aryl ring π-π stacking interactions a supramolecular structure is formed in 1.

引用

页码：1149 / 1152

页数：4