Breaking 12% efficiency in flexible organic solar cells by using a composite electrode

被引:0
作者
Guang Zeng [1 ,2 ]
Jingwen Zhang [1 ]
Xiaobin Chen [1 ]
Hongwei Gu [3 ]
Yaowen Li [1 ]
Yongfang Li [1 ,4 ]
机构
[1] Laboratory of Advanced Optoelectronic Materials, College of Chemistry, Chemical Engineering and Materials Science,Soochow University
[2] College of Materials Science and Engineering, Nanchang Hangkong University
[3] College of Chemistry, Chemical Engineering and Materials Science, Soochow University
[4] Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences
基金
中国国家自然科学基金;
关键词
flexible electrodes; flexible organic solar cells; silver nanowire; composite electrode; power conversion efficiency;
D O I
暂无
中图分类号
TM914.4 [太阳能电池]; TB33 [复合材料];
学科分类号
0805 ; 080502 ;
摘要
The performance of flexible organic solar cells(OSCs)significantly relies on the quality of transparent flexible electrode.Here,we used silver nanowires(AgNWs)with various weight ratios to dope high-conductive poly(3,4-ethylenedioxythiophene):polystyrene sulfonate(PH1000)to optimize the optical and electronic properties of PH1000 film.A high-quality flexible composite electrode PET/Ag-mesh/PH1000:AgNWs-20 with smooth surface,a low sheet resistance of 6Ω/sq and a high transmittance of 86%at 550-nm wavelength was obtained by doping 20 wt%AgNWs to PH1000(PH1000:AgNWs-20).The flexible OSCs based on the PET/Ag-mesh/PH1000:AgNWs-20 electrode delivered a power conversion efficiency(PCE)of12.07%with an open circuit voltage(V;)of 0.826 V,a short-circuit current density(J;)of 20.90 m A/cm;and a fill factor(FF)of69.87%,which is the highest reported PCE for the flexible indium-tin oxide(ITO)-free OSCs.This work demonstrated that the flexible composite electrodes of PET/Ag-mesh/PH1000:AgNWs are promising alternatives for the conventional PET/ITO electrode,and open a new avenue for developing high-performance flexible transparent electrode for optoelectronic devices.
引用
收藏
页码:851 / 858
页数:8
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