One New 3D Pillared-layer Ag(Ⅰ)-Coordination Framework Based on a Unique 1D Ag2O2 Ribbon: Synthesis,Crystal Structure and Luminescent Properties

被引：0

作者：

王建芳 ^{[1
]}

吴亚盘 ^{[1
,2
]}

伍学谦 ^{[1
]}

文国选 ^{[1
]}

王超 ^{[1
]}

机构：

[1] College of Materials and Chemical Engineering,Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials,China Three Gorges University

[2] Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education,College of Chemistry & Materials Science,Northwest University

来源：

结构化学 | 2016年 / 35卷 / 08期

关键词：

Ag(Ⅰ) coordination polymer; 3D pillared-layer framework; 1D Ag2O2 ribbon; fsc topology;

D O I：

10.14102/j.cnki.0254-5861.2011-1040

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

A new 3D Ag(I) coordination polymer {[Ag(AZDB)0.5(bpe)0.5]·H2O}n(1) has been papared by azobenzene-3,3?-dicarboxylicate(H2AZDB), 1,2-bis(4-pyridyl)ethylene(bpe) and silver salts via hydrothermal method. The compound was fully characterized by single-crystal X-ray diffraction, elemental analyses, infrared spectrum(IR), powder X-ray diffraction(PXRD) and thermogravimetric analysis(TGA). The strucrural analysis indicate that compound 1 shows a 3D pillared-layer framework constructed from a unique 1D Ag2O2ribbon and pyridyl/carboxylicate mixed system, which features a 2-nodal(4, 6)-connected fsc net with a(44·610·8)(44·62) topology.Moreover, the photoluminescent properties have also been discussed.

引用

页码：1238 / 1244

页数：7

共 3 条

[1] Metal-organic frameworks based upon non-zeotype 4-connected topology[J] . Dong-Sheng Li,Ya-Pan Wu,Jun Zhao,Jian Zhang,Jack Y. Lu.Coordination Chemistry Reviews . 2014
[2] Influential factors on assembly of first-row transition metal coordination polymers[J] . Shi-Yao Yang,Hong-Bo Yuan,Xiao-Bin Xu,Rong-Bin Huang.Inorganica Chimica Acta . 2013
[3] Solvent- and temperature-driven synthesis of three Cd（II） coordination polymers based on 3,3′-azodibenzoic acid ligand: Crystal structures and luminescent properties[J] . Lei-Lei Liu,Lin Liu,Jun-Jie Wang.Inorganica Chimica Acta . 2012

← 1 →