Calix[6]arene-bismetalloporphyrins as Enzyme Models for P450 V. Catalytic Performance in Epoxidation of Styrene

被引：0

作者：

李东红

陈淑华

赵华明

机构：

[1] The Faculty of Chemistry

[2] Sichuan University

[3] Chengdu

[4] Sichuan

[5] China

来源：

ChineseJournalofChemistry | 2003年 / 06期

关键词：

calixarene bismetalloporphyrins; cytochrome P450 model compound; styrene; epoxidation;

D O I：

暂无

中图分类号：

O621.25 [];

学科分类号：

070303 ; 081704 ;

摘要：

In this paper the catalytic performance of the calixarene bismetalloporphyrins in the epoxidation of styrene was studied. The influence of phase transfer catalyst, pH value, buffer agent, substrate concentration, substituent on the benzene ring of porphyrin, and the central metal ion, etc. , on the reaction rates were investigated meticulously. The results showed that the calixarene bismetalloporphyrins had a much higher catalytic activity than that of the corresponding metalloporphyrins.

引用

页码：683 / 686+593 +593

页数：5

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