SYNTHESIS AND CRYSTAL STRUCTURE OF DINUCLEAR IRON CARBONYL DERIVATIVE （μ-SC6H5） (μ-P （SC6H5）2) Fe2 （CO）5 (P-（SC6H5）3)

被引：0
|
作者：
Wu Bin-Fang Su Han-Quan Yan Xiu-Ying Hu Xing Liu Qi-WangFuzhou Laboratory of Structural Chemistry
机构：
来源：
结构化学 | 1992年 / 05期
关键词：
Fe2; SC6H5; SYNTHESIS AND CRYSTAL STRUCTURE OF DINUCLEAR IRON CARBONYL DERIVATIVE; CO;
D O I：
10.14102/j.cnki.0254-5861.1992.05.006
中图分类号：
学科分类号：
摘要：
The reaction of Fe3(CO)12 with P(SPh)3 yields the tile compound. C41H30Fe2O5P2S6, Mr = 968. 65, monoclinic, space group, P21/n, a = 14. 449(9), b = 18. 046(11), c=16.871(10)(?), β=98. 76°, V = 4348(?)3, Z = 4, Dc=1. 480g/ cm3, λ(MoKα) = 0. 71073(?) The structure was determined by direct methods and difference Fourier syntheses and refined by full-matrix least-squares procedure to R = 0.084, Rw = 0.144 for 4059 reflections. Fe(1)-Fe(2) = 2. 576(6), Fe(2)-P(2) = 2.194(9)(?). The dihedral angle between the Fe(l)SFe(2) and Fe(1)PFe(2) planes is 81. 9°. The other one (dihedral angle between SFe(1)P and SFe(2)P planes) is 75. 2°.
引用
收藏
页码：339 / 342
页数：4
相关论文
共 50 条
12345