SynthesisandCharacterizaionofaNewInorganic-organicSulfateCompound——CrystalStructureof[Ni（H2O）6][H2N（C2H4）2NH2]（SO4）2

被引：0

作者：

MENG He XING Yan FU Yunlong SHI Zhan and PANG Wenqin State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University Changchun P R China ^{[130023
]}

机构：

来源：

ChemicalResearchinChineseUniversities | 2004年 / 01期

关键词：

Inorganic-organic compound; Crystal structure; Nickel sulfate;

D O I：

暂无

中图分类号：

O627 [元素有机化合物];

学科分类号：

070303 ; 081704 ;

摘要：

Ni（H2O）6][H2N（C2H4）2NH2]（SO4）2 is an inorganic-organic compound with a new open framework synthesized by hydrothermal method, and characterized by means of single-crystal diffraction and spectroscopic data. The compound crystallized in a monoclinic space group P21/n with a=1.29089（2） nm, b=1.06301（3） nm, c=1.33202（4） nm, β=114.0870（10）°, V=1.67127（8） nm 3, Z=4, and was solved by using the direct method and the least-squares refinement converged at R=0.0214[I>2σ（I）]. The structure consists of isolated Ni（H2O）6 octahedra and SO4 tetrahedra, with both of them hydrogen-bonded to piperazine cations.

引用

页码：1 / 5

页数：5

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