Hydrothermal Synthesis,Crystal Structure and Thermal Stability of [Ni（phen）3]·(C8H12O4)·（H2O）14

被引：0
作者：
张少华
李昶红
杨颖群
李薇
李玉林
机构：
[1] Department of Chemical Engineering,Hunan Institute of Technology
[2] Department of Chemistry and Materials Science,Hengyang Normal University
来源：
结构化学 | 2008年 / 27卷 / 12期
关键词：
nickel(II) complex; hydrothermal synthesis; thermal stability property;
D O I：
10.14102/j.cnki.0254-5861.2008.12.017
中图分类号：
O627.8 [第Ⅷ族元素有机化合物];
学科分类号：
070303 ; 081704 ;
摘要：
One novel complex [Ni(phen)3]·(C8H12O4)·(H2O)14 with hexane dicarboxylic acid and 1,10-phenanthroline has been hydrothermally synthesized and characterized.Crystal data:monoclinic,space group C2/c,a = 2.3475(5),b = 1.2208(2),c = 1.9499(4) nm,β = 114.682(3)°,V = 5.0778(16) nm3,Dc = 1.339 g/cm3,Z = 4,μ(MoKα) = 0.458 mm-1,F(000) = 2168,GOOF = 1.014,R = 0.0401 and wR = 0.0961.The nickel(II) center in the title complex is coordinated with six nitrogen atoms of three 1,10-phenanthroline molecules,giving a distorted octahedral coordination geometry.However,the nickel(II) ion does not coordinate to the hexane dicarboxylic acid.The complex molecules form a 3D structure through hydrogen bonds.TG analysis shows that the title complex is stable below 240.0 ℃.
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页码：1427 / 1430
页数：4
相关论文
共 13 条
  • [1] Huang,L.,Zhang,L.P.,Jin,L.P. Chemical Journal of Chinese Universities . 2004
  • [2] Yang,Y.,Zhang,J.N.,Luo,S.R.,Song,X.H.,Li,Q. Acta Chinica Sinica . 2006
  • [3] Yang,Y.Q.,Li,C.H.,Kuang,D.Z.,Guo,D.C.,Chen,Z.M.,Chen,M.S.,Kuang,Y.F. Chinese J.Inorg.Chem . 2006
  • [4] Yang,Y.Q.,Li,C.H.,Kuang,D.Z.,Guo,D.C.,Chen,Z.M.,Chen,M.S.,Kuang,Y.F. Chinese J.Inorg.Chem . 2006
  • [5] Zhu,P.H. Chinese J.Fine Chemical Intermediates . 2005
  • [6] Li,C.H.,He,X.M.,Li,W.,Yang,Y.Q. Chinese J.Inorg.Chem . 2007
  • [7] Kuang,Y.F.,Li,C.H.,Li,W.,Yang,Y.Q. Chinese J.Struct.Chem . 2007
  • [8] Nakamota, K,Translated by Huang, D. R.,Translated by Wang, R. Q.Infrared and Raman Spectra of Inorganic and Coordination Compounds. . 1986
  • [9] Zheng,Y.Q.,Lin,J.L. Z.Anorg.Allg.Chem . 2002
  • [10] Li,Z.F.,Zheng,Y.Q. Z.Kristallogr.New Cryst.Struct . 2005
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