Preparation, Characterization and Catalytic Properties of S2O82-/ZrO2 Supported by Tungsten Carbide

被引:0
作者
XUE Hua-xin and CHEN Jian-min ** Department of Environmental Science & Engineering
机构
关键词
n-Pentane; Isomerization; S2O; 2-8/ZrO2; Tungsten carbide;
D O I
暂无
中图分类号
O643.3 [催化];
学科分类号
081705 ;
摘要
A WC-supported S2O 2-8/ZrO2(PSZ) catalyst was prepared and characterized by means of XRD, BET, FTIR and XPS. The isomerization of n-pentane over the catalyst was investigated as well. The results show that the skeletal isomerization and the crack of n-pentane proceed simultaneously on WC-supported S2O 2-8/ZrO2 catalyst. The addition of tungsten carbide showed a significant enhancement in the activity and stability of the catalyst for n-pentane isomerization. The catalyst showed evidently a better activity than S2O 2-8/ZrO2 supported by Pt and WO3. The results can be interpreted by the existence of the tungsten oxycarbide compound(WCxOy) with carbidic, oxide and acidic sites.
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页码:68 / 72
页数:5
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