SEPARATION OF HEXAACETATES OF S-1-METHYLPHEN-ETHYLAMINO DERIVATIVE OF;
STUDIES ON RESOLUTION OF RACEMIC GOSSYPOL RACEMIC GOSSYPOL;
GOSSYPOL;
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摘要:
<正> This paper reports the resolution of racemic gossypol to optically active enantiomery by condensationof (±) gossypol with S-1-methylphenethylamine, followed by subsequent actetylation and hydrolysis. Sev-en isomers of hexaacetate of di-S-1-methylphenet-thylamino gossypol have been obtained by chromatog-raphy on silica gel, and also structures of the acetates have been determined.