Degradation of 2,4-Dichlorophenol Catalyzed by Ultrasound-Assisted Laccase

被引:0
作者
郭慧文 [1 ,2 ]
张淑琴 [1 ,2 ]
任大军 [1 ,2 ]
邓志群 [1 ,2 ]
黄朝凡 [1 ,2 ]
康晨 [1 ,2 ]
机构
[1] College of Resource and Environmental Engineering,Wuhan University of Science and Technology
[2] Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources,Wuhan University of Science and Technology
关键词
ultrasonic; laccase; catalysis; 2,4-dichlorophenol(2,4-DCP); oxidation; degradation;
D O I
10.19884/j.1672-5220.2018.06.003
中图分类号
X592 [农用化学物质、有毒化学物质污染及其防治]; O643.32 [催化反应];
学科分类号
082803 ; 081705 ;
摘要
Laccase possesses a good degradation effect on organic pollutants,but it is too long to achieve the desired effect. In order to improve the treatment effect of laccase on degradation of organic pollutants,2,4-dichlorophenol( 2, 4-DCP) was selected as a treatment target in the study. This study investigated a newtechnique for catalyzing the degradation of 2,4-DCP, that is,ultrasound-assisted laccase catalysis. The optimal experimental parameters such as p H,ultrasonic power,duty cycle and laccase concentration were determined under optimized experimental conditions. The results showed that the optimum conditions for degradation of 2,4-DCP were that pH = 5. 5,the input power was 105 W,the duty cycle was 50% and the laccase concentration was0. 4 U/m L. The degradation rate of 2,4-DCP reached 77. 5% under the optimum conditions at 4 h. When in ultrasonic environment,the enzymatic activity of laccase could be stimulated and improved.Compared with conventional methods,this technique significantly promoted the degradation rate of 2,4-DCP while reduced action time. Furthermore, no newpollutant was introduced into the degradation process. Therefore,ultrasound-assisted laccase catalysis is an environmentally friendly technique to degrade pollutants.
引用
收藏
页码:453 / 457
页数:5
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