SynthesisandStructureofanti-ConfigurationComplex[Cu（tssb）2]·2[（H3O）Cl]·4H2O

被引：2

作者：

ZHANG ShuHuaa JIANG YiMin b LIU Zhenga ZHOU ZhongYuanc a Department of Material and Chemical Engineering Guilin Institute of Technology Guilin China b Department of Chemistry Guangxi Normal University Guilin China c Department of Applied Biology and Chemical Technology Hongkong Polytechnic University Hongkong ^{[541004
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机构：

来源：

结构化学 | 2004年 / 08期

关键词：

copper complex; taurine-salicylaldehyde Schiff base; crystal structure; anti-; configuration;

D O I：

10.14102/j.cnki.0254-5861.2004.08.009

中图分类号：

O627 [元素有机化合物];

学科分类号：

070303 ; 081704 ;

摘要：

The title complex [Cu(tssb)2]2[(H3O)Cl]4H2O (C18H34Cl2CuN2O14S2) (tssb = tau- rine salicylaldehyde Schiff base) has been synthesized by the reaction of taurine salicylaldehyde Schiff base (tssb) and copper acetate in water-ethanol. Its single-crystal structure was determined by X-ray diffraction method. The crystal structure belongs to triclinic, space group P1 with a = 0.7407(1), b = 1.3329(3), c = 1.5736(3) nm, ?= 103.800(4), ?= 95.030(4), ?= 104.416(4)? Mr = 701.06, V = 1.4433(5) nm3, Z = 2, Dc = 1.613 g/cm3, = 1.153 mm-1 and F(000) = 726. The compound is an infinitely expanding three-dimensional network connected with hydrogen bonds. The Cu(Ⅱ) atom is coordinated by two nitrogen and two oxygen atoms to form a distorted planar coordination compound which adopts anti-configuration because two sulfonic acid groups are posi- tioned diagonally on a plane.

引用

页码：882 / 885+841 +841

页数：5