Influence of Bi addition on dynamic recrystallization and precipitation behaviors during hot extrusion of pure Mg

Low material cost and high extrudability for ensuring price competitiveness with Al alloys, as well as excellent mechanical properties, are essential for expanding the application range of Mg extrudates. Bi is a promising alloying element for developing extruded Mg alloys that satisfy such requirements. Bi is inexpensive, exhibits a high solubility limit, and forms a thermally stable Mg3Bi2phase, which improves the commercial viability and enables the high-speed extrusion of Mg–Bi alloys. In this study, the effects of Bi addition on the dynamic recrystallization(DRX) and dynamic precipitation behaviors during hot extrusion of a pure Mg and the resultant microstructure and mechanical properties of the extruded materials were investigated. The addition of 6 wt% and 9 wt% Bi to a pure Mg yielded numerous fine Mg3Bi2precipitates during the early stage of hot extrusion. Consequently, the area fraction of dynamic recrystallized(DRXed) grains decreased because of DRX-behavior suppression by the Zener pinning effect.However, the DRXed grain size was substantially reduced through the grain-boundary pinning effect.The size and number of undissolved Mg3Bi2particles in the homogenized billets increased when the Bi content was increased, which resulted in increased DRX fractions owing to the enhanced levels of particle stimulated nucleation. Bi addition yielded considerable strength improvement of the extruded pure Mg. However, the extruded Mg–Bi binary materials were less ductile than the extruded pure Mg material. This lower ductility resulted from the cracking at twins formed in the coarse un DRXed grains of the Mg-6Bi material and the cracking at large undissolved Mg3Bi2particles in the Mg-9Bi material.