Hydrothermal Synthesis and Structural Characterization of a Novel 3-D Open Framework Zinc Phosphate Microporous Compound(C5N2H14)·[Zn3(OH2)(PO4)2(HPO4)]

被引：0

作者：

彭成栋 ^{[1
]}

李雅丝 ^{[1
]}

庄婷婷 ^{[1
]}

殷凡文 ^{[1
]}

曾庆新 ^{[1
]}

机构：

[1] College of Chemistry and Chemical Engineering, Fuzhou University

来源：

Chinese Journal of Structural Chemistry | 2014年 / 03期

关键词：

zinc; phosphate; hydrothermal synthesis; 3D open framework; microporous compound;

D O I：

10.14102/j.cnki.0254-5861.2014.03.002

中图分类号：

O614.241 [];

学科分类号：

070301 ; 081704 ;

摘要：

One novel organically templated zincophophate(C5N2H14)·[Zn3(OH2)(PO4)2(HPO4)] has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction together with elemental analysis, infrared spectroscopy, thermogravimetric analysis, and powder X-ray diffraction. The title compound crystallizes in the monoclinic space group P21/n, with a = 9.7904(11), b = 14.0287(14), c = 11.8651(13) , β = 104.690(3), V = 1576.4(3) 3, Z = 4, T = 296(2) K, Mr = 601.31 and Dc = 2.533 g/cm3. The compound consists of a macroanionic [Zn3(OH2)(PO4)2(HPO4)]2- framework and(C5N2H14)2+ cations, and its structure is built up from ZnO3(OH2), ZnO4, HPO4 and PO4 tetrahedral units that result in 4, 8 and 10-ring channels.

引用

页码：333 / 338

页数：6

共 6 条

[1]

Extra‐Large‐Pore Zeolites: Bridging the Gap between Micro and Mesoporous Structures[J] . JiuxingJiang,JihongYu,AvelinoCorma.Angewandte Chemie International Edition . 2010 (18)

[2]

Syntheses, structures and magnetic properties of two new one-dimensional cobalt (II) phosphites with organic amines acting as ligands[J] . Gaijuan Li,Yan Xing,Shuyan Song.Journal of Solid State Chemistry . 2008 (4)

[3] Crystal structures and spectroscopic properties of a new zinc phosphite cluster and an unexpected chainlike zinc phosphate obtained by hydrothermal reactions [J].

Lin, Zhi-En ;

Fan, Wei ;

Gu, Jinlou ;

Okubo, Tatsuya .

JOURNAL OF SOLID STATE CHEMISTRY, 2007, 180 (03) :981-987

[4]

Hydrothermal synthesis and structural characterization of novel organically templated zincophosphites:[C 6 H 4 (CH 2 NH 3 ) 2]·[Zn 3 (HPO 3 ) 4] and[CH 3 CH 2 CH 2 NH 3] 2 ·[Zn 3 (HPO 3 ) 4][J] . Dong Zhang,Zhan Shi,Wenjun Dong,Wensheng Fu,Lei Wang,Guanghua Li,Shouhua Feng.Journal of Solid State Chemistry . 2003 (1)

[5]

(C 6 H 16 N 2 )Zn 3 (HPO 3 ) 4 H 2 O: a new layered zinc phosphite templated by diprotonated trans -1,4-diaminocyclohexane[J] . Yu Wang,Jihong Yu,Yi Li,Yu Du,Ruren Xu,Ling Ye.Journal of Solid State Chemistry . 2002

[6]

Anorganische Materialien mit offenen Gerüsten[J] . Angewandte Chemie . 1999 (22)

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