EFFECTOFOXYGENCONTENTSONOXYGENPOTENTIALSOFH2O-H2ANDH2O-H2-INERTSGASMIXTURES

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作者
FANG Zheng CHEN Xinmin(H.M.Chen) Central South University of Technology
Changsha
China FANG Zheng
Associate Professor
Department of Chemistry
Central South University of Technology
Changsha
China
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关键词
gas equilibration method; H2O-H2; H2O-H2-inerts; oxygen potential;
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摘要
<正> By taking the effect of oxygen contents into account,a new set of formulae which representsthe oxygen potentials of H2O-H2 and H2O-H2-inerts gas mixtures has been derived.Classi-cal representation is only a particular case of it.Some of the variables affecting equilibriumatmosphere when trace oxygen is present and optimum preparation of the gas mixtures to min-imize errors have been discussed.The reliability of some of previous equilibrium experimentsunder the oxygen potentials controlled by H2O-H2 or H2O-H2-inerts gas mixtures has alsobeen criticized.
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页码:1 / 9
页数:9
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