SIMULATION STUDY OF CO-ASSEMBLY OF ABC TRIBLOCK COPOLYMER/NANOPARTICLE INTO MULTICOMPARTMENT HYBRIDS IN SELECTIVE SOLVENT

被引：0
|
作者：
Jie Cui [1 ]
Wei Li [1 ]
Wei Jiang [1 ]
机构：
[1] State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
来源：
ChineseJournalofPolymerScience | 2013年 / 31卷 / 09期
基金：
中国国家自然科学基金;
关键词：
Co-assembly; Triblock copolymer; Nanoparticle; Multicompartment hybrid; Self-consistent field theory;
D O I：
暂无
中图分类号：
TB383.1 [];
学科分类号：
摘要：
Co-assembly of ABC linear triblock copolymer/nanoparticle into bump-surface multicompartment hybrids in selective solvent was studied through self-consistent field theory (SCFT) simulation. Results from three-dimensional SCFT simulation showed that the hybrid morphology depended on the length and number of grafted chains, whereas the number and shape of bumps relied on nanoparticle size. Moreover, the simulation results showed that the length and number of grafted chains had equivalent effect on hybrid morphology. Calculated results indicated that entropy was a more important factor than enthalpy in the co-assembly.
引用
收藏
页码：1225 / 1232
页数：8
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