Two N-donor Auxiliary Ligands Mediated Zn(Ⅱ) Coordination Polymers Incorporating 5-Nitro-1,2,3-benzenetricarboxylate Ligand: Syntheses, Crystal Structures, and Luminescent Properties

被引：0

作者：

张甜 ^{[1
]}

赵一静 ^{[1
]}

秦秋沛 ^{[1
]}

机构：

[1] College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Functionoriented Porous Materials, Luoyang Normal University

来源：

ChineseJournalofStructuralChemistry | 2020年 / 39卷 / 06期

关键词：

coordination polymer; 5-nitro-1,2,3-benzenetricarboxylic acid; bis(imidazol-1-yl)methane; N-(4-pyridylmethyl)imidazole; photoluminescent properties;

D O I：

10.14102/j.cnki.0254-5861.2011-2547

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

Two N-donor auxiliary ligands mediated Zn（Ⅱ） coordination polymers, namely, {[Zn（Hnbta）-（bimm）]（3H;O）};（1） and {[Zn;（nbta）(pyim)（H;O）]（2H;O）};（2）(H;nbta = 5-nitro-1,2,3-benzenetricarboxylic acid, bimm = bis（imidazol-1-yl）methane and pyim = N-（4-pyridylmethyl）imidazole), have been prepared by the hydrothermal reaction. Their structures were determined by single-crystal X-ray diffraction analysis, elemental analyses and infrared spectra. Compound 1 possesses a one-dimensional（1D） chain structure, while compound 2 features a two-dimensional（2D） network. In addition, they both exhibit high thermal stabilities and photoluminescent properties in the solid, and can be explored as potential luminescent materials.

引用

页码：1051 / 1056

页数：6

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