CRYSTAL AND MOLECULAR STRUCTURE OF (μ-PhS) (μ-σ,π-CH3CH = CH)Fe2(CO)6

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作者
Song Li-Cheng Hu Qing-MciDepartment of Chemistry
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基金
美国国家科学基金会;
关键词
Fe; PhS; CRYSTAL AND MOLECULAR STRUCTURE OF; CH3CH; CO;
D O I
10.14102/j.cnki.0254-5861.1990.01.008
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摘要
The crystal and molecular structure of (μ-PhS) (μ-σ, n-CH3CH = CH)-Fe2(CO)6 has been determined by X - ray diffraction technique. The complex has chemical formula of C15H10O6SFe2 and Mr=129. 99. The crystals are monoclinic,space group P21/c,with α=11. 789(2),b= 7. 159(1),c = 20. 890(4) A ;β = 100. 89(2);V = 1731. 32 A3;Z=4,Dc=1. 65g·cm-3;F(000) = 863. 86. The final R and Rw equal 0. 0315 and 0. 0405 respectively for 2527 observed unique reflections.
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页码:34 / 37
页数:4
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