Asymmetric transfer hydrogenation of ketones catalyzed by nickel complex with new PNO-type ligands

被引：2
作者：
Zhen Rong Dong~(a
机构：
来源：
Chinese Chemical Letters | 2012年 / 23卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Nickel complex; NPO-type ligand; Asymmetric transfer hydrogenation; Ketones;
D O I：
暂无
中图分类号：
O643.32 [催化反应];
学科分类号：
081705 ;
摘要：
The new polydentate mixed-N,P,O chiral ligands have been synthesized by the condensation of bis（o-formylphenyl）- phenylphosphane and R-phenylglycinol in CHCl;,and fully characterized by IR,NMR and EIMS spectra.These ligands were employed with a simple Ni complex Ni（PPh;）;Cl;in situ as catalytic systems for asymmetric transfer hydrogenation of ketones,and the corresponding optical alcohols were obtained with up to 84%ee under mild conditions.
引用
收藏
页码：533 / 536
页数：4
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