A pillar[5]arene-based side-chain pseudorotaxanes and polypseudorotaxanes as novel fluorescent sensors for the selective detection of halogen ions

被引：0

作者：

Shu Sun ^{[1
,2
]}

Jian-Bing Shi ^{[1
]}

Yu-Ping Dong ^{[1
]}

Chen Lin ^{[2
]}

Xiao-Yu Hu ^{[2
]}

Le-Yong Wang ^{[2
]}

机构：

[1] School of Materials Science and Engineering, Beijing Institute of Technology

[2] Key Laboratory of Mesoscopic Chemistry of MOE, Center for Multimolecular Chemistry, School of Chemistry and Chemical Engineering, Nanjing University

来源：

ChineseChemicalLetters | 2013年 / 24卷 / 11期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

Pillar[5]arene; Polypseudorotaxanes; Fluorescent sensor; Halogen ions detection;

D O I：

暂无

中图分类号：

O657.1 [电化学分析法];

学科分类号：

070302 ; 081704 ;

摘要：

A pseudorotaxane and its polypseudorotaxanes formed between pillar[5]arene moieties and noctylpyrazinium cations as novel fluorescent sensors for the selective detection of halogen ions were reported.A collapse of these pillar[5]arene-based pseudorotaxanes and polypseudorotaxanes occurred upon the addition of Cl,Br,and I(tetrabutylammonium salts),respectively,leading to their fluorescence recovery.The fluorescence enhancement of the pseudorotaxane and the polypseudorotaxanes increases in the order of I<Br<Cl,and the differences in fluorescence intensity could be easily distinguished by naked eyes under UV light illumination.

引用

页码：987 / 992

页数：6

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