BF3·Et2O promoted conjugate addition of ethanethiol to electron-deficient alkynes

被引：1
|
作者：
Qing Fa Zhou
机构：
来源：
Chinese Chemical Letters | 2012年 / 23卷 / 06期
基金：
中国国家自然科学基金;
关键词：
Vinyl thioether; Electron-deficient alkyne; Conjugate addition; Synthesis;
D O I：
暂无
中图分类号：
O621.2 [有机化合物性质];
学科分类号：
摘要：
An effective method for the synthesis of vinyl thioethers through the conjugate addition of ethanethiol to electron-deficient alkynes promoted by BFEtOhas been developed.Electron-deficient internal alkynes react with ethanethiol in this system to yield mainly Z-isomer of vinyl thioether adducts,while electron-deficient terminal alkynes afford mainly E-isomer of vinyl thioether adducts.
引用
收藏
页码：639 / 642
页数：4
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